With your emissions being that high, I don’t think that sitting for a long period is the only problem you have. I would start with, has a Nutter bypass been done? If so, was it done correctly?
Even more importantly, check your EGR valve. If it is still on the engine and someone did the Nutter bypass only to leave it connected in its stock set up, that is probably part of the problem. You can reuse the EGR valve but it needs the vacuum lines re-routed. Even if no Nutter was preformed, check the valve for proper function (i.e. the diaphragm still modulates with increased RPM’s). If possible, take it off and clean it and the seating surfaces. A deflective EGR will cause rough idle problems as well.
The next thing to consider with regards to emissions is now old are the plugs? Are they gapped correctly? Do they appear black (running rich)? You may even consider a higher out-put coil so you can open the spark gap up more. More spark= more fuel burned off/ less emissions.
Keep us posted….