Not knowing what Jeep model and engine you have, you should either have a Automatic tensioner or a Manual tensioner. IF you have an automatic tensioner, the only remedy is to replace it. i don't see the relation of the Defroster with the serpentine belt issue unless you do have a bearing problem with the Alternator, which you said you have already checked. The Manual tensioner could be tightened up by loosening the tensioner pulley bolt with a 14 or 15mm wrench then loosen the tensioner bolt that pulls the pulley tighter. Make your adjustments then re-tighten the pulley bolt.