I get 19mpg on average, which is much more than I expected (2020 JGC V6). I drive 70% highway, the rest city, usually 60-70mph on the highway, and don't have a heavy foot. The sticker on the JGC says 19mpg in the city, I get that on average gas tank with mixed driving, which the sticker claims should get 21mpg. I don't get 21mpg even on pure highway driving unless it's straight and 60mph exactly for a long period, then I get about 23mpg, which is still less than the claimed 24mpg highway that the sticker claims.
And I do use ESS.
I gave up trying, I just drive without looking at that damned addictive gauge with the green showing me when I'm under average, argh, that this is hard to turn off, but now it's only on when wife drives me around (she's learning to drive) that way she sees if she's driving properly, and she wants to save gas too lol, or the Jeep, I think.
EDIT: Sorry, I misread, thought you had a 2020, not 2000, and was about to ask what kind of 4.0 is that in a 2020. Seems to me that's great mileage for a 2000 big 6, as it's just a bit worse than a brand new Pentastar.